By 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki
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8 in the form of the characteristic curve. Dubinin (1960) assumed a distribution of the Gaussian type for the characteristic curve and derived the following, which is called DubininRadushkevich equation. Adsorption equilibrium relation of benzene on two types of activated carbon are plotted by the Langmuir plot and the Dubinin plot in Fig. 9(a) and (b). Apparently, the Dubinin equation gives a better regression to the data of Hasz (1969). Later this equation was generalized by Dubinin and Astakhov (1970) to the following form.
28. 4. Adsorption Isotherms for Multicomponent Systems When two or more adsorbable components exist with the possibil~tyof occupying the same adsorpt~onsites, isotherm relationships become more complex. The srmplest is extension of the Langmuir type rsotherm by assuming no interaction between adsorbing molecules. In the case of two components, the extended Langmurr isotherm (Markham and Benton, 1931) is given as Thls equatron enables qurck est~matron of equilibrium relatrons of Adsorprron Isotherms for Multtcomponent Systems 57 multicomponent adsorption from Langmuir parameters determined from the single component isotherm of each component.
For several CMS's, this method is applied and comparison of pore Micropore size (A ) Fig. 19. Micropore size distributions of carbon molecular sieve adsorbents determined by the molecular probe method. sizes is tried (Fig. 19). 1 A), were tried and from the amount adsorbed of each component, the pore volume for the micropores larger than this size can be determined. 3. Surface area lnternal surface area of microporous adsorbents is often used as one of the measures to describe the degree of development of pores.
Adsorption engineering by 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki