Download e-book for iPad: Amidines and Imidates: Volume 1 (1975) by

ISBN-10: 0470771496

ISBN-13: 9780470771495

ISBN-10: 0471669237

ISBN-13: 9780471669234

Content:
Chapter 1 basic and theoretical elements of amidines and imidic acid derivatives (pages 1–84): G. Hafelinger
Chapter 2 structure, configurational and conformational points, and chiroptical homes of imidic acid derivatives (pages 85–155): G. Fodor and B. A. Phillips
Chapter three Detection and resolution of imidic acid derivatives (pages 157–188): W. H. Prichard
Chapter four Rearrangements related to imidsc acid derivatives (pages 189–240): C. G. McCarty and L. A. Garner
Chapter five The electrochemistry of Imsdic esters and amidines (pages 241–253): Henning Lund
Chapter 6 organic reactions and pharmaceutical makes use of of imidic acid derivatives (pages 255–281): Raymond J. Grout
Chapter 7 instruction and artificial makes use of of amidines (pages 283–348): Jean?Albert Gautier, Marcel Miocque and Claude Combet Farnoux
Chapter eight Kinetics and mechanisms of reactions of amidines (pages 349–384): Robert H. de Wolfe
Chapter nine Imidates together with cyclic imidates (pages 385–489): Douglas G. Neilson
Chapter 10 The chemistry of amidrazones (pages 491–545): okay. M. Watson and D. G. Neilson
Chapter eleven Estimation of the thermochemistry of imidic acid derivatives (pages 547–564): Robert Shaw
Chapter 12 complicated formation, H?bonding and basicity of imidic acid derivatives (pages 565–617): J. Sevcik and F. Grambal

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Extra info for Amidines and Imidates: Volume 1 (1975)

Sample text

T h e infrared spectra of both types of compounds have been thoroughly inspected and interpreted by PrevorSek 63*118. 1. N-Monosubstituted amidines N-Phenylamidines show two N H bands 63 appearing near 3500 and 3400 cm - l . The observed frequencies are in close agreement with those found for the asymmetrical and symmetrical valence vibrations in formamide119 a t 3533 and 341 1 c m -l , respectively, which indicates that N phenylaniidines contain a terminal amino group, i x . almost exclusive dominance of the tautomeric structure (52).

Aspects of amidines and imidic acid derivatives 37 In Table 13 the calculated dipole moments are compared with experimental values (see Section 11, B) as far as available. The agreement is not too good, because in the PPP x-electron theory the effect of 3-bond moments is completely neglected, but the order of magnitude of experimental dipole monents is predicted correctly. IV. E L E C T R O N I C SPECTRA A. Amidines and Amidinium Salts The unconjugated amidine group should give rise to a n -> x* and a transition in the ultraviolet or vacuum ultraviolet region of the absorption spectrum.

E 12. 2 by J. E. Bloor and B. R. Gilsonaoon a CDC 3300 comp 'Zcntrum fur Datenverarbeitung' of the University of Tubingen. 36 G . -c P E m N S 4 1. Aspects of amidines and imidic acid derivatives 37 In Table 13 the calculated dipole moments are compared with experimental values (see Section 11, B) as far as available. The agreement is not too good, because in the PPP x-electron theory the effect of 3-bond moments is completely neglected, but the order of magnitude of experimental dipole monents is predicted correctly.

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Amidines and Imidates: Volume 1 (1975)


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